| 2024-05-19 19:00 | J37 | Villarreal |  | - |  | Real Madrid | | h2h |
| 2024-05-11 16:15 | J35 | Villarreal | | 3-2 |  | Sevilla | Alexander Sorloth 30' 90', Yerson Mosquera 84'; Youssef En-Nesyri 26' (P) 44' | |
| 2024-04-28 18:30 | J33 | Villarreal | | 3-0 |  | Rayo Vallecano | Alexander Sorloth 18' 74', Yerson Mosquera 69' | |
| 2024-04-01 21:00 | J30 | Villarreal | | 1-2 |  | Atlético de Madrid | Alexander Sorloth 50'; Axel Witsel 9', Saúl Ñíguez 87' | |
| 2024-03-17 16:15 | J29 | Villarreal | | 1-0 |  | Valencia | Jorge Cuenca 54' | |
| 2024-03-14 18:45 | 1/8 | Villarreal | | 3-1 |  | Marseille | Étienne Capoue 32', Alexander Sorloth 54', Yerson Mosquera 85'; Jonathan Clauss 90' | |
| 2024-03-03 14:00 | J27 | Villarreal | | 5-1 |  | Granada | Alexander Sorloth 7' 19' 66', Étienne Capoue 32', Gonçalo Guedes 47'; Theo Corbeanu 90' | |
| 2024-02-16 21:00 | J25 | Villarreal | | 1-1 |  | Getafe | Alberto Moreno 56'; Nemanja Maksimovic 24' | |
| 2024-02-04 14:00 | J23 | Villarreal | | 0-0 |  | Cádiz | | |
| 2024-01-20 16:15 | J21 | Villarreal | | 1-1 |  | Mallorca | Alexander Sorloth 45'; Javier Llabrés 90' | |
| 2023-12-20 21:30 | J18 | Villarreal | | 3-2 |  | Celta de Vigo | Alfonso Pedraza 13', Aïssa Mandi 40', Dani Parejo 48' (P); Tasos Douvikas 52', Strand Larsen 57' | |
| 2023-12-09 18:30 | J16 | Villarreal | | 0-3 |  | Real Sociedad | Mikel Merino 38', Martin Zubimendi 41', Takefusa Kubo 45' | |
| 2023-12-06 21:00 | Grp.F | Villarreal | | 0-0 |  | Maccabi Haifa | | |
| 2023-11-30 21:00 | Grp.F | Villarreal | | 3-2 |  | Panathinaikos | Álex Baena 29', Santi Comesaña 34', José Luis Morales 47'; Sebastian Palacios 66', Fotis Ioannidis 81' | |
| 2023-11-26 14:00 | J14 | Villarreal | | 3-1 |  | Osasuna | José Luis Morales 57' 71' 80'; Alejandro Catena 78' | |
| 2023-11-05 18:30 | J12 | Villarreal | | 2-3 |  | Athletic Bilbao | Gerard Moreno 86', Alexander Sorloth 87'; Iñigo de Galarreta 2', Nico Williams 22', Iñaki Williams 30' | |
| 2023-10-22 18:30 | J10 | Villarreal | | 1-1 |  | Alavés | Gerard Moreno 65' (P); Samu Omorodion 48' | |
| 2023-10-08 14:00 | J9 | Villarreal | | 1-2 |  | Las Palmas | Gerard Moreno 90'; Saúl Coco 45', Marc Cardona 51' (P) | |
| 2023-10-05 21:00 | Grp.F | Villarreal | | 1-0 |  | Rennes | Alexander Sorloth 36' | |
| 2023-09-27 19:00 | J7 | Villarreal | | 1-2 |  | Girona | Dani Parejo 49' (P); Artem Dovbyk 56', Eric García 61' | |
| 2023-09-17 16:15 | J5 | Villarreal | | 2-1 |  | Almería | Gerard Moreno 45', Alexander Sorloth 90'; Sergio Akieme 44' | |
| 2023-08-27 17:30 | J3 | Villarreal | | 3-4 |  | Barcelona | Juan Foyth 26', Alexander Sorloth 40', Álex Baena 50'; Pablo Gavi 12', Frenkie de Jong 15', Ferrán Torres 68', Robert Lewandowski 71' | |
| 2023-08-13 19:30 | J1 | Villarreal | | 1-2 |  | Real Betis | Jorge Cuenca 61'; Ayoze Pérez 20', Willian José 90' | |
17/05 - 20:00
